March, 1963.  Stan Lee, Don Heck. Origin and first appearance of Iron Man in "Iron Man Is Born!" 

September, 1963 Disney movie tie-in.

June, 1987. Special Double-Sized Issue. Peter David, Alan Kupperburg & Tom Morgan.  "The Hobgoblin Revealed!"

August, 1968.  Stan Lee, Gene Colan.  "In Combat With Captain America!"

Origin retold: Daredevil. "In Combat With Captain America!"

Title changes to Superman Family with #164.

(A-1 #76).

December, 1940.

November, 1947 "Adventure In Opto"

Cover: Steve Ditko.

"The Shrinking Formula!"

Joker.

Carl Barks cover and art.

December, 1964.  Stan Lee, Don Heck.  "The Mighty Avengers Meet Spider-Man!"

Movie photo cover (Charles Starrett in Horsemen Of The Sierras).

July, 1977.  Bill Mantlo, George Tuska.  "Ten Rings To Rule The World!"  Anniversary issue.

February, 1966 Disney movie photo cover.

First appearance of Gambit (5 page story).

September-October, 1955.  Anniversary issue. 

1st: Blade The Vampire Slayer.

August, 1962 Movie photo cover.

March,  1991.  Gerry Conway,  Sal Buscema.  "Dedication (Or, "Jonah Goes To Pieces!")

April, 1956 Previous title: Bo.

100 page digest.

July, 1966 Disney movie tie-in.

June, 1947 This one-shot's back cover touted features on Ace Harlem, Sugarfoot, and Snakeoil in the following issue, which, alas, never was published. And apparently not many of this issue, a 15-cent oddity, were published; Gerber gives the book an almost unheard of rating of 9 ("very rare"). To further enhance the allure, Overstreet advises the book is "seldom found in fine or mint condition; many copies have brown pages." To date, CGC hasn't certified a copy with a grade higher than 7.5.

History
All-Negro Comics, Inc was started by Orrin C. Evans with partners Harry Saylor, Bill Driscoll, and a few others. He hoped to address the absence of black heroes in popular culture and to set "high moral and educational standards." Although they had great ambitions, they were only able to publish one issue of All-Negro Comics. A second issue was planned and artwork made for the comic, but the publishers could not find enough vendors willing to sell their comics and they soon folded.

September, 1970. Stan Lee, Jack Kirby. Cover & art: Jack Kirby. "To Smash The Inhumans!"

NAd.

September, 1974.

July, 1955 "Mystery Of Furnace Valley" Photo cover.

MSe RTh. Re-intro Toro.

December, 1953 The Red Rover. HRN #115. (12/53)

August, 1952

App: Wolverine.

JDb BRo. 1st: Bumblebee, Harlequin II.

"The Four Dooms!" 

Origin (pt.3): Galactus.

June, 1979.  David Michelinie, John Romita Jr.  "Casino Fatale!"

August, 1957

March, 1976.  Len Wein,  Sal Buscema.  "The Sandman Always Strikes Twice."

"Rags To Riches." Cover: Carl Barks.

February, 1944 "Down Mexico Way"

January-February, 1951.  "The Wonder Woman Story!" Origin retold: Wonder Woman.

April, 1956 "The Secret Of The Flames"

August, 1956.  "The Secret Wonder Woman!" 1st "5000 Prizes" issue.

(#16).

February, 1985.  Tom DeFalco, Ron Frenz.  "The Sins Of My Father!"

Disney Cheerios Premium.

Photo cover.

Spring, 1945.

Firelord, Galactus, Watcher.

"Death In The Family", part 3. Death: Robin.

App: Supersnipe.

February, 1944.

"Ghost Train!"

August, 1958.  "The Forest Of Giants!"

1st & Origin: Parasite.

January, 1969.  "Shanghaied In Space!" 

Special anniversary issue.

App: Venom.

"And The Rocking Horse Thieves"

(10104-404)

April, 1971.  Stan Lee, Gene Colan.  "Now Rides The Ghost Of El Condor!"

Hulk vs. The Thing.

November, 1979.  Steven Grant, John Byrne.  "Wings And Arrows!"

September, 1963 "The All-Powerful Super-Skrull!"

March, 1965. Stan Lee, Steve Ditko. Ringmaster appears and the first appearance of Princess Python in "The Clown And His Masters Of Menace!"

Low number distributed.

January, 1972. Roy Thomas, Barry Smith. "Web of the Spider-God!"

1st: Boomerang.

Donald Duck With Huey, Dewey & Louie, "The Seafarers."

X-Men appearance.

October, 1975.

July, 1959 TV photo cover.

Santa Claus.

February, 1969. Arnold Darke, Don Heck, Vinnie Colletta.  "Die, Traitor!"

. Cover: "Spirit Of '76" by Will Eisner.

November, 1949 

Art: John Byrne.

March, 1954 Photo cover.

Spider-Man.

Reprint: Tales To Astonish #27 (1st Ant-Man). Becomes Marvel's Greatest Comics.

October, 1969.   Stan Lee, Jack Kirby.  "The Thing..Enslaved!"

Art: Bob Powell.

Joker cover & story by Neal Adams (9/73).

November, 1967 King-Size Special. 1st: solo Silver Surfer story.

July, 1953 Pitcairn's Island. HRN #110.

September-October, 1954.  "The Boy Of 100 Faces!"

November, 1966 King Size Special.

AprJune. 1951 Title changes to Indian Chief with #3.

ELa DMi. App: Venom.

G.I. Juniors.

April, 1938 Blondie.

"Junior Commandos"

February, 1973.  1st: revival of original Captain Marvel since the Golden-Age.

"The Winged Maidens Of Venus"

"Battle For Fairyland!"

Popeye.

"A Christmas For Shacktown."

May, 1950.  (#33 on cover) Cody Of The Pony Express, movie/serial tie-in.

November, 1967. Stan Lee, John Romita. Dr. Octopus appears in "The Tentacles And The Trap!"

January, 1973.  Roy,  John Buscema.  "Battleground: The Baxter Building!"

February, 1936 1st Donald Duck cover.

100 page Giant. (8/58)

August, 1973. Gerry Conway, Gil Kane. Spider-Man battles Luke Cage in "...Just A Man Called Cage!"

October 1947 Swiss Family Robinson. HRN #42.

Photo cover.

TV photo cover.

SBu RTh. Brutivac.

"Shall Man Survive?"

End: Dale Keown art.

September, 1968. Stan Lee, John Romita. "The Vulture's Prey!"

April, 1976.  Len Wein, Irving W.  "...And The Freak Shall Inherit The Earth!"

December, 1939 Pinocchio.

"The Sleepers In The Crypt"

January, 1965.  Stan Lee, Don Heck.  "This Hostage Earth!"

April, 1949 Cover/Art: Bob Powell in all issues.

2nd printing.

March, 1957

July 1948 Title changes to Wild Western with #3.

"The Dwarfs Of Didona!"

"The Volcano Maker!"

"Menace Of The Sky Creature!"

April, 1969. Stan Lee, John Buscema. "And Who Shall Mourn For Him?"

August, 1952 TV tie-in.

Double size. Hulk battles The Thing.